3-bromodibenzo[b,d]thiophene → HCID 19887836, compound

HRID 654646Notes

Reaction equation

HRID 654646 reaction equation
Br[C:2]1[CH:3]=[CH:4][C:5]2[C:9]3[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=3[S:7][C:6]=2[CH:14]=1.[CH3:15][Sn:16](C)([CH3:39])[C:17]1C=CC2C3C=CC(CO[Si](C(C)(C)C)(C)C)=CC=3OC=2C=1>>[CH3:15][Sn:16]([CH3:39])([CH3:17])[C:2]1[CH:3]=[CH:4][C:5]2[C:9]3[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=3[S:7][C:6]=2[CH:14]=1

Participants

3

Reactant 2

HCID 134156163-bromodibenzo[b,d]thiopheneHCID 19437716HCID 19437716, compound

Product 1

HCID 19887836HCID 19887836, compoundYield 82%

Procedure

Using the procedure described in Example 316, but substituting 3-bromodibenzothiophene for the bromodibenzofuran 10 of Example 316, provided the title compound in 82% yield.

Sources & evidence

ORD record
ord-17e1c54989e446888ec70e578971c897
Source dataset
uspto-grants-1992_07
Patent number
US05132420

Reaction notes

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