Benzyl Alcohol → 3-Benzyloxy-5-nitroiodobenzene

HRID 654812Notes

Reaction equation

HRID 654812 reaction equation
[CH2:1]([OH:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+:9]([C:12]1[CH:13]=[C:14]([I:21])[CH:15]=[C:16]([N+]([O-])=O)[CH:17]=1)([O-:11])=[O:10]>>[CH2:1]([O:8][C:16]1[CH:15]=[C:14]([I:21])[CH:13]=[C:12]([N+:9]([O-:11])=[O:10])[CH:17]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 244Benzyl AlcoholHCID 2352691-Iodo-3,5-dinitrobenzene

Product 1

HCID 200819643-Benzyloxy-5-nitroiodobenzeneYield 54%

Procedure

Using the procedure described in the first paragraph of Note c. below Table I in Example 2, benzyl alcohol was reacted with 3,5-dinitroiodobenzene to give 3-benzyloxy-5-nitroiodobenzene in 54% yield, m.p. 79°-80° C.

Sources & evidence

ORD record
ord-a0c34f7bbf63457b89ddecf98e587f4e
Source dataset
uspto-grants-1992_07
Patent number
US05134148

Reaction notes

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