HCID 11481239, compound → 5-(2-Napthyl)pentan-1-ol

HRID 654938Notes

Reaction equation

HRID 654938 reaction equation
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:11]#[C:12][CH2:13][CH2:14][CH2:15][OH:16]>[Pd].C(OCC)C>[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][OH:16]

Participants

4

Reactant 1

HCID 11481239HCID 11481239, compound

Product 1

HCID 177688985-(2-Napthyl)pentan-1-ol

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 3283Diethyl EtherSolvent

Procedure

A mixture of 5-(2-napthyl)-4-pentyn-1-ol (520 mg, 247 mmol) and 10% palladium on activated carbon in ethyl ether (50 ml) was stirred at room temperature under a hydrogen atmosphere for 2 days. Solvent removal, after filtration through celite, gave the titled compound as a light yellow oil.

Workup

  1. customSolvent removal
  2. filtrationafter filtration through celite

Sources & evidence

ORD record
ord-918eab5a3c9a436c8241e35d5a3714c1
Source dataset
uspto-grants-1992_07
Patent number
US05134128

Reaction notes

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