HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium bis(trimethylsilyl)amide → Isophthalonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium bis(trimethylsilyl)amide | HCID 2724254 | — |
| Reactant | HCID 19887125 | HCID 19887125 | — |
| Reactant | HCID 19887147 | HCID 19887147 | — |
| Product | Isophthalonitrile | HCID 12276 | — |
Reaction Steps
kk) by using 3,5-dicyanobenzylidenetriphenylphosphorane prepared in situ by means of 3,5-dicyanobenzyltriphenylphosphonium bromide and sodium bis(trimethylsilyl)amide there is obtained 5-[(Z)-2-(1R,4S,5S,8R)-4,8-dimethyl-7-oxo-2,3-dioxabicyclo[3.3.1]nonan-4-yl]vinyl]isophthalonitrile [m.p. 85°];
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05134240 |
| Source dataset | uspto-grants-1992_07 |
| ORD ID | ord-4af9701447b547ff96e654b9faa4c337 |
| Source note | uspto-grants-1992_07 |