8-Methylsulfonyl-12-acetoxy-16-heptadecenoate → HCID 21317550, compound

HRID 65652Notes

Reaction equation

HRID 65652 reaction equation
[CH3:1][S:2]([CH:5]([CH2:16][CH2:17][CH2:18][CH:19]([O:25]C(=O)C)[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH:11][C:12]([O:14]C)=[O:13])(=[O:4])=[O:3].CS(C(CCCC(OC(=O)C)CCCC=C)CCCCCCC([O-])=O)(=O)=O>>[CH3:1][S:2]([CH:5]([CH2:16][CH2:17][CH2:18][CH:19]([OH:25])[CH2:20][CH2:21][CH2:22][CH:23]=[CH2:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])(=[O:3])=[O:4]

Participants

3

Procedure

The synthesis of this compound is carried out as in Example 3, Step E, except that the methyl 8-methylsulfonyl-12-acetoxyheptadecenoate is replaced by an equivalent quantity of 8-methylsulfonyl-12-acetoxy-16-heptadecenoate.

Workup

  1. customThe synthesis of this compound

Sources & evidence

ORD record
ord-99ff9a29d80348c0941689a82e16389b
Source dataset
uspto-grants-1978_12
Patent number
US04128564

Reaction notes

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