참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | tert-BUTYL CHLORIDE | HCID 10486 | — |
| 반응물 | Pyrene | HCID 31423 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 용매 | Water | HCID 962 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Pyrene, 1-(1,1-dimethylethyl)- | HCID 187956 | 51.1% |
반응 단계
In a reaction vessel, 50.0 g (0.25 mol) of pyrene, 27.6 g (0.30 mol) of tert-butyl chloride, and 200 ml of methylene chloride were charged, and the resulting mixture was cooled to 0° C. Next, 35.3 g (0.27 mol) of aluminum chloride was charged, followed by stirring at room temperature for 2 hours. Then, iced water and methylene chloride were added, and an organic layer was extracted, washed with water, dried over magnesium sulfate, and recrystallized to produce 33 g of tert-butylpyrene crystals in a yield of 51%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08071993B2 |
|---|
| 출처 데이터셋 | uspto-grants-2011_12 |
|---|
| ORD ID | ord-c1dab17752ad443b8a4feaa787b65f85 |
|---|
| 출처 메모 | uspto-grants-2011_12 |
|---|
