Bromide ion → HCID 58045844, compound

HRID 657976Notes

Reaction equation

[C:1]([C:5]1[CH:6]=[C:7]([C:14](=[O:16])[CH3:15])[CH:8]=[C:9]([OH:13])[C:10]=1[O:11][CH3:12])([CH3:4])([CH3:3])[CH3:2].O=O.[Br-].[C:20]([O:23][CH2:24][CH2:25][CH2:26][CH2:27]Br)(=[O:22])[CH3:21]>>[C:20]([O:23][CH2:24][CH2:25][CH2:26][CH2:27][O:13][C:9]1[CH:8]=[C:7]([C:14](=[O:16])[CH3:15])[CH:6]=[C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])[C:10]=1[O:11][CH3:12])(=[O:22])[CH3:21]

Participants

Reactant 4

HCID 259Bromide ion

HCID 977Oxygen

HCID 784911-Butanol, 4-bromo-, 1-acetate

HCID 581369461-(3-Tert-butyl-5-hydroxy-4-methoxyphenyl)ethanone

Product 1

HCID 58045844HCID 58045844, compoundYield 100.5%

Procedure

1-(3-tert-Butyl-5-hydroxy-4-methoxyphenyl)ethanone (O3.070; 6.9 g) was converted and worked up analogously to O2.071. The bromide used was 4-bromobutyl acetate (7.27 g). 10.5 g of the title compound were obtained.

Sources & evidence

ORD record: ord-c3b27ad00bd24fe397cd64d6f5e76f8a
Source dataset: uspto-grants-2011_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08076336B2

Reaction notes

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