1-Butanol → Butyl 4-(tert-butylperoxy)-4-methylpentan-2-yl carbonate

HRID 65973Notes

Reaction equation

HRID 65973 reaction equation
C([OH:5])CCC.N1C=[CH:10][CH:9]=[CH:8][CH:7]=1.Cl[C:13]([O:15][CH:16]([CH3:27])[CH2:17][C:18]([CH3:26])([O:20][O:21][C:22]([CH3:25])([CH3:24])[CH3:23])[CH3:19])=[O:14]>C(OCC)C>[C:13](=[O:5])([O:14][CH2:7][CH2:8][CH2:9][CH3:10])[O:15][CH:16]([CH3:27])[CH2:17][C:18]([CH3:26])([O:20][O:21][C:22]([CH3:25])([CH3:24])[CH3:23])[CH3:19]

Participants

5

Reactant 3

HCID 2631-ButanolHCID 1049PyridineHCID 19612317HCID 19612317, compound

Product 1

HCID 23346606Butyl 4-(tert-butylperoxy)-4-methylpentan-2-yl carbonate

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a solution of 8.1 g. (0.11 mole) of n-butyl alcohol and 7.9 g. (0.1 mole) of pyridine in diethyl ether cooled to 10°±1° C was added a solution of 27.0 g. (0.1 mole) 1,3-dimethyl-3-(t-butylperoxy)butyl chloroformate. The reaction temperature was controlled at 15°±1° C during the addition.

Workup

  1. additionwas added a solution of 27.0 g
  2. additionThe reaction temperature was controlled at 15°±1° C during the addition

Sources & evidence

ORD record
ord-48bbfee49992416ea207df2115b8016f
Source dataset
uspto-grants-1978_12
Patent number
US04129700

Reaction notes

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