HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → HCID 58150860, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | Ammonium Hydroxide | HCID 14923 | — |
| Reactant | 1,4-Benzenediamine, N-methyl-, dihydrochloride | HCID 79373 | — |
| Reactant | Phenol, 3-amino-2-chloro-6-methyl-, hydrochloride | HCID 157640 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 58150860 | HCID 58150860 | 88.4% |
Reaction Steps
A mixture of 2 g of N-methylbenzene-1,4-diamine dihydrochloride, 2 g of 3-amino-2-chloro-6-methylphenol hydrochloride, 20 ml of water, 20 ml of ethanol and 7.6 ml of 9% aqueous hydrogen peroxide solution, a mixture brought to pH 9.5 with 20% ammonium hydroxide in water, is stirred at ambient temperature for 5 hours. 2.5 g of 3-amino-2-chloro-6-methyl-4-{[4-(methylamino)phenyl]imino}cyclohexa-2,5-dien-1-one (1n) are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08083809B2 |
| Source dataset | uspto-grants-2011_12 |
| ORD ID | ord-aba0638abbb34100bb2f4af7042157e6 |
| Source note | uspto-grants-2011_12 |