Benzene, (2-methyl-2-propenyl)- → HCID 57777403, compound

HRID 660507Notes

Reaction equation

HRID 660507 reaction equation
C([O:8][C:9]1[CH:14]=[C:13](I)[CH:12]=[CH:11][C:10]=1[N:16]1[S:20](=[O:22])(=[O:21])[N:19](CC[Si](C)(C)C)[C:18](=[O:29])[CH2:17]1)C1C=CC=CC=1.[CH3:30][C:31](=[CH2:39])[CH2:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1>>[OH:8][C:9]1[CH:14]=[C:13]([CH2:30][CH:31]([CH3:39])[CH2:32][C:33]2[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=2)[CH:12]=[CH:11][C:10]=1[N:16]1[S:20](=[O:21])(=[O:22])[NH:19][C:18](=[O:29])[CH2:17]1

Participants

3

Reactant 2

HCID 18687Benzene, (2-methyl-2-propenyl)-HCID 667569375-(2-Benzyloxy-4-iodophenyl)-1,1-dioxo-2-(2-trimethylsilanylethyl)-1,2,5-thiadiazolidin-3-one

Product 1

HCID 57777403HCID 57777403, compound

Procedure

The title compound is prepared from 5-(2-benzyloxy-4-iodophenyl)-1,1-dioxo-2-(2-trimethylsilanylethyl)-1,2,5-thiadiazolidin-3-one and (2-methylallyl)-benzene analogous to Example 51: (M−1)−=359. HPLC retention time=1.65 min (Method A).

Sources & evidence

ORD record
ord-10eb7d0d00eb4ae0bc232f41cafb182e
Source dataset
uspto-grants-2011_12
Patent number
US08084448B2

Reaction notes

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