HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide dimethyl acetal → Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide dimethyl acetal | HCID 78373 | — |
| Reactant | 1,5,9-Triazacyclododecane | HCID 470778 | — |
| Product | Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene | HCID 12641659 | 73.1% |
Reaction Steps
In a manner similar to that of Example 1 (C), 5.00 g (29.2 mmol) of 1,5,9-triazacyclododecane and 3.48 g of dimethylformamide dimethyl acetal were reacted to give 3.87 g of 1,5,9-triazatricyclo[7.3.1.05,13 ]tridecane as a clear, colorless liquid, bp 93° (three fractions) (0.35 mm), which solidified on standing at room temperature. One fraction was analyzed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04130715 |
| Source dataset | uspto-grants-1978_12 |
| ORD ID | ord-d742f01c8a9a451f8198c8a3497b4046 |
| Source note | uspto-grants-1978_12 |