Sodium Hydroxide → HCID 131711093, compound

HRID 66222Notes

Reaction equation

HRID 66222 reaction equation
COCC[O:5][C:6](=[O:82])[C:7]1[CH:19]=[C:18]([NH:20][S:21]([C:24]2[CH:25]=[C:26]3[C:31](=[CH:32][CH:33]=2)[C:30]([S:34]([NH:37][C:38]2[CH:39]=[C:40]([C:51]([O:53]CCOC)=[O:52])[CH:41]=[C:42]([CH:50]=2)[C:43]([O:45]CCOC)=[O:44])(=[O:36])=[O:35])=[CH:29][C:28]([S:58]([NH:61][C:62]2[CH:63]=[C:64]([C:75]([O:77]CCOC)=[O:76])[CH:65]=[C:66]([CH:74]=2)[C:67]([O:69]CCOC)=[O:68])(=[O:60])=[O:59])=[CH:27]3)(=[O:23])=[O:22])[CH:17]=[C:9]([C:10]([O:12]CCOC)=[O:11])[CH:8]=1.[OH-].[Na+:84]>>[Na+:84].[Na+:84].[Na+:84].[Na+:84].[Na+:84].[Na+:84].[C:30]1([S:34]([NH:37][C:38]2[CH:39]=[C:40]([C:51]([O-:53])=[O:52])[CH:41]=[C:42]([CH:50]=2)[C:43]([O-:45])=[O:44])(=[O:35])=[O:36])[C:31]2[C:26](=[CH:25][C:24]([S:21]([NH:20][C:18]3[CH:17]=[C:9]([C:10]([O-:12])=[O:11])[CH:8]=[C:7]([CH:19]=3)[C:6]([O-:82])=[O:5])(=[O:22])=[O:23])=[CH:33][CH:32]=2)[CH:27]=[C:28]([S:58]([NH:61][C:62]2[CH:63]=[C:64]([C:75]([O-:77])=[O:76])[CH:65]=[C:66]([CH:74]=2)[C:67]([O-:69])=[O:68])(=[O:59])=[O:60])[CH:29]=1

Participants

3

Reactant 2

HCID 14798Sodium HydroxideHCID 544288385,5',5"-[1,3,6-Naphthalenetriyltris(sulfonylimino)]triisophthalic acid hexakis(2-methoxyethyl)ester

Product 1

HCID 131711093HCID 131711093, compound

Procedure

A mixture of 9.05 g of the product of Example 3 and 45 ml of 2N sodium hydroxide is stirred at room temperature for 45 minutes. The solution is filtered, the filtrate is neutralized with 2.5 ml of glacial acetic acid, and diluted with 250 ml of ethanol. The product formed is collected by filtration, washed with ethanol followed by ether and dried to give 7.85 g of the product of the Example as a yellow powder.

Workup

  1. filtrationThe solution is filtered
  2. additiondiluted with 250 ml of ethanol
  3. customThe product formed
  4. filtrationis collected by filtration
  5. washwashed with ethanol
  6. customdried

Sources & evidence

ORD record
ord-9b30a4a6b6c341d7b2e5985214429d19
Source dataset
uspto-grants-1978_12
Patent number
US04130660

Reaction notes

Loading…