HRID66980

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14797

Potassium hydroxide

HKO

结构：CC(CCCCCC1=CCCC1=O)(C(=O)O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]

HCID178442515

未命名化合物

结构：CCOC(=O)C(C)(CCCCCC1=CCCC1=O)C(=O)OCC.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]

HCID178471343

未命名化合物

PRODUCTS

生成物

结构：CC(CCCCCC1=CCCC1=O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]

HCID178442516

未命名化合物

PROCEDURE

实验过程

Saponification of 2-(6,6-dicarbethoxyheptyl)-2-cyclopentenone methoxime (Example 96) with potassium hydroxide by the method of Example 20 is productive of 2-(6,6-dicarboxyheptyl)-2-cyclopentenone methoxime, decarboxylation of which in the manner of Example 63 provides the subject compound.

WORKUP

后处理

customprovides the subject compound

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e808d35fae3341b3b8d3257d4e13a616
来源数据集: uspto-grants-1982_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04343949
来源说明: uspto-grants-1982_08

反应 SMILES

[C:1]([C:6](C(OCC)=O)([CH3:18])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[C:13](=[O:17])[CH2:14][CH2:15][CH:16]=1)([O:3]CC)=[O:2].[CH:24]1[C:25](/[CH:40]=[N:41]/[OH:42])=[CH:26][CH:27]=[N+:28]([CH2:30][N+:31]2[CH:36]=[CH:35][C:34](/[CH:37]=[N:38]/[OH:39])=[CH:33][CH:32]=2)[CH:29]=1.[Br-:43].[Br-].[OH-].[K+].C(C(C(O)=O)(C)CCCCCC1C(=O)CCC=1)(O)=O.C1C(/C=N/O)=CC=[N+](C[N+]2C=CC(/C=N/O)=CC=2)C=1.[Br-].[Br-]>>[C:1]([CH:6]([CH3:18])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[C:13](=[O:17])[CH2:14][CH2:15][CH:16]=1)([OH:3])=[O:2].[CH:26]1[C:25](/[CH:40]=[N:41]/[OH:42])=[CH:24][CH:29]=[N+:28]([CH2:30][N+:31]2[CH:32]=[CH:33][C:34](/[CH:37]=[N:38]/[OH:39])=[CH:35][CH:36]=2)[CH:27]=1.[Br-:43].[Br-:43]