1-n-Octadecyl-2,2,6,6-tetramethyl-4-piperidinol → HCID 131712799, compound

HRID 67044Notes

Reaction equation

HRID 67044 reaction equation
[CH2:1]([C:3]1[CH:8]2[CH2:9][CH:5]([CH2:6][CH2:7]2)[C:4]=1[CH2:10][CH3:11])[CH3:2].[CH2:12]([N:30]1[C:35]([CH3:37])([CH3:36])CC(O)[CH2:32][C:31]1([CH3:40])[CH3:39])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>>[CH2:12]([N:30]1[C:31]([CH3:32])([CH3:40])[CH2:39][CH:1]([C:3]2[CH:8]3[CH2:9][CH:5]([CH2:6][CH2:7]3)[C:4]=2[CH:10]2[CH2:40][C:31]([CH3:32])([CH3:39])[N:30]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[C:35]([CH3:36])([CH3:37])[CH2:11]2)[CH2:2][C:35]1([CH3:36])[CH3:37])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]

Participants

3

Reactant 2

HCID 537066531-n-Octadecyl-2,2,6,6-tetramethyl-4-piperidinolHCID 53943896Diethyl bicyclo [2.2.1]hept-5-ene

Product 1

HCID 131712799HCID 131712799, compound

Procedure

In an analogous manner is also reacted diethyl bicyclo [2.2.1]hept-5-ene-endo,exo-2,3-dicarboxylate with 1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidinol to give wax-like bis-(1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidyl) bicyclo[2.2.1]hept-5-ene-endo,exo-2,3-dicarboxylate. (Example 9)

Sources & evidence

ORD record
ord-cc44b03cebb44e549c4cdf1dc72accfc
Source dataset
uspto-grants-1982_08
Patent number
US04344877

Reaction notes

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