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2-(p-Biphenylyl)-2-penten-4-ol → 2-(p-Biphenylyl)-pentan-4-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-(p-Biphenylyl)-2-penten-4-ol | HCID 70545419 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 2-(p-Biphenylyl)-pentan-4-ol | HCID 70544256 | — |
反応手順
To a pressure vessel, mixture of 0.675 g. of 2-(p-biphenylyl)-2-penten-4-ol (obtainable by Example 1) and 0.5 g. 10% palladium on carbon in 175 ml. of ethanol, is added hydrogen at about 2 at. pressure via below pressure hydrogenation. The catalyst is then removed, and the solution is evaporated to give a colorless oil which solidifies on standing to give solid 2-(p-biphenylyl)-pentan-4-ol, m.p. 53° C., which may also be designated 4-(p-biphenylyl)-pentan-2-ol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04344966 |
| 出典データセット | uspto-grants-1982_08 |
| ORD ID | ord-d98945abbc9d4ac79925b6a232ef6a80 |
| 出典メモ | uspto-grants-1982_08 |