Pyridine → (4-Formyl-2-oxo-3,3a,4,5,6,6a-hexahydrocyclopenta[b]furan-5-yl) benzoate

HRID 672846Notes

Reaction equation

HRID 672846 reaction equation
[C:11]([c:12]1[cH:13][cH:14][cH:15][cH:16][cH:17]1)(=[O:18])[O:19][CH:20]1[CH:21]([CH2:29][OH:30])[CH:22]2[CH:23]([O:24][C:25](=[O:27])[CH2:26]2)[CH2:28]1.[CH2:31]([Cl:32])[Cl:33].[CH3:34][c:35]1[cH:36][cH:37][cH:38][cH:39][cH:40]1.[O:1]=[Cr:2](=[O:3])=[O:4].[cH:5]1[cH:6][cH:7][n:8][cH:9][cH:10]1>>[C:11]([c:12]1[cH:13][cH:14][cH:15][cH:16][cH:17]1)(=[O:18])[O:19][CH:20]1[CH:21]([CH:29]=[O:30])[CH:22]2[CH:23]([O:24][C:25](=[O:27])[CH2:26]2)[CH2:28]1

Participants

6

Reactant 5

HCID 1049PyridineHCID 1140TolueneHCID 6344DichloromethaneHCID 14915Chromium TrioxideHCID 33491634-(hydroxymethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Product 1

HCID 3368300(4-Formyl-2-oxo-3,3a,4,5,6,6a-hexahydrocyclopenta[b]furan-5-yl) benzoate

Sources & evidence

ORD record
ord-2f3cb18780814ea6ae9af70ce0a6d6bb
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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