Carbonate Ion → 1,1-Dimethylethyl (6-formyl-3-pyridinyl)methylcarbamate

HRID 680219Notes

Reaction equation

HRID 680219 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:8]=[O:9])[n:6][cH:7]1.[C:19](=[O:20])([O-:21])[O-:22].[CH3:10][NH:11][C:12]([O:13][C:14]([CH3:15])([CH3:16])[CH3:17])=[O:18].[CH:33](=[CH:34][C:35]([CH:36]=[CH:37][c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)=[O:44])[c:45]1[cH:46][cH:47][cH:48][cH:49][cH:50]1.[CH:51](=[CH:52][C:53]([CH:54]=[CH:55][c:56]1[cH:57][cH:58][cH:59][cH:60][cH:61]1)=[O:62])[c:63]1[cH:64][cH:65][cH:66][cH:67][cH:68]1.[CH:69](=[CH:70][C:71]([CH:72]=[CH:73][c:74]1[cH:75][cH:76][cH:77][cH:78][cH:79]1)=[O:80])[c:81]1[cH:82][cH:83][cH:84][cH:85][cH:86]1.[Cs+:23].[Cs+:24].[O:25]1[CH2:26][CH2:27][O:28][CH2:29][CH2:30]1.[Pd:31].[Pd:32]>>[c:2]1([CH2:10][NH:11][C:12]([O:13][C:14]([CH3:15])([CH3:16])[CH3:17])=[O:18])[cH:3][cH:4][c:5]([CH:8]=[O:9])[n:6][cH:7]1

Participants

8

Reactant 7

HCID 19660Carbonate IonHCID 23938Palladium2×HCID 312751,4-DioxaneHCID 95417Dibenzylidene acetone3×HCID 104967Cesium cation2×HCID 527635tert-Butyl methylcarbamateHCID 98775625-Bromopyridine-2-carbaldehyde

Product 1

HCID 866181111,1-Dimethylethyl (6-formyl-3-pyridinyl)methylcarbamate

Sources & evidence

ORD record
ord-28575337ff624443849b7b993d21a766
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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