Dichloromethane → [4,5,6-Triacetyloxy-2-(methoxymethyl)oxan-3-yl] acetate

HRID 680881Notes

Reaction equation

HRID 680881 reaction equation
[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([O:7][C:8]([CH3:9])=[O:10])[CH:11]([O:12][C:13]([CH3:14])=[O:15])[CH:16]([O:17][C:18]([CH3:19])=[O:20])[CH:21]([CH2:23][OH:24])[O:22]1.[Cl:28][CH2:29][Cl:30].[N+:25](=[N-:26])=[CH2:27]>>[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([O:7][C:8]([CH3:9])=[O:10])[CH:11]([O:12][C:13]([CH3:14])=[O:15])[CH:16]([O:17][C:18]([CH3:19])=[O:20])[CH:21]([CH2:23][O:24][CH3:27])[O:22]1

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 9550DiazomethaneHCID 349482[(2R,3R,4S,5R,6S)-4,5,6-triacetyloxy-2-(hydroxymethyl)oxan-3-yl] acetate

Product 1

HCID 523853[4,5,6-Triacetyloxy-2-(methoxymethyl)oxan-3-yl] acetate

Sources & evidence

ORD record
ord-351111a0ca7b4ff6aa6d701d97d47b7a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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