3-Bromophenanthrene → Phenanthren-3-ylboronic acid

HRID 68498Notes

Reaction equation

HRID 68498 reaction equation
[CH:1]1[C:14]2[CH:13]=[CH:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][C:2]=1[B:15]([OH:17])[OH:16].BrC1C=CC2C=CC3C(C=2C=1)=CC=CC=3>>[CH:4]1[C:5]2[CH:14]=[CH:13][C:12]3[C:11](=[CH:10][CH:9]=[CH:8][CH:7]=3)[C:6]=2[CH:1]=[C:2]([B:15]([OH:16])[OH:17])[CH:3]=1

Participants

3

Reactant 2

HCID 967673-BromophenanthreneHCID 46835781Phenanthren-2-ylboronic acid

Product 1

HCID 46835783Phenanthren-3-ylboronic acid

Procedure

Synthesis was performed in the same manner as in the synthesis of phenanthrene-2-boronic acid except that commercially available 3-bromophenanthrene was used instead of 2-iodophenanthrene.

Workup

  1. customSynthesis

Sources & evidence

ORD record
ord-aa60755b534c4acb9883132e38617f00
Source dataset
uspto-grants-2014_09
Patent number
US08822041B2

Reaction notes

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