Phenanthren-3-ylboronic acid → 3-(4-Bromophenyl)phenanthrene

HRID 68499Notes

Reaction equation

HRID 68499 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:21]=[CH:20][C:19]3[C:18]4[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=4)[CH:12]=[CH:11][C:10]=3[CH:9]=2)=[CH:4][CH:3]=1.C1C2C=CC3C(=CC=CC=3)C=2C=C(B(O)O)C=1>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]2[CH:21]=[CH:20][C:19]3[CH:18]=[CH:17][C:12]4[C:11]([C:10]=3[CH:9]=2)=[CH:16][CH:15]=[CH:14][CH:13]=4)=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 46835783Phenanthren-3-ylboronic acidHCID 581942352-(4-Bromophenyl)phenanthrene

Product 1

HCID 580381073-(4-Bromophenyl)phenanthrene

Procedure

Synthesis was performed in the same manner as in the synthesis of 2-(4-bromophenyl)phenanthrene except that phenanthrene-3-boronic acid was used instead of phenanthrene-2-boronic acid.

Workup

  1. customSynthesis

Sources & evidence

ORD record
ord-86eff152ec3e408ebc3b01e462e44178
Source dataset
uspto-grants-2014_09
Patent number
US08822041B2

Reaction notes

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