1-Bromophenanthrene → Phenanthreneboronic acid

HRID 68505Notes

Reaction equation

C1C2C=CC3C(=CC=CC=3)C=2C=CC=1[B:15]([OH:17])[OH:16].Br[C:19]1[C:32]2[CH:31]=[CH:30][C:29]3[C:24](=[CH:25][CH:26]=[CH:27][CH:28]=3)[C:23]=2[CH:22]=[CH:21][CH:20]=1>>[C:19]1([B:15]([OH:17])[OH:16])[C:32]2[CH:31]=[CH:30][C:29]3[C:24](=[CH:25][CH:26]=[CH:27][CH:28]=3)[C:23]=2[CH:22]=[CH:21][CH:20]=1

Participants

Reactant 2

HCID 139338801-Bromophenanthrene

HCID 46835781Phenanthren-2-ylboronic acid

Product 1

HCID 10082252Phenanthreneboronic acid

Procedure

Synthesis was performed in the same manner as in the synthesis of phenanthrene-2-boronic acid except that 1-bromophenanthrene was used instead of 2-iodophenanthrene.

Workup

customSynthesis

Sources & evidence

ORD record: ord-7994827070c341bcba9d8d3d38a24134
Source dataset: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08822041B2

Reaction notes

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