HRID68648

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID12088

4-Carboxybenzaldehyde

C8H6O3

结构：C[Si](C)(C)CCOCn1ccnc1CNCc1nccn1COCC[Si](C)(C)C

HCID67162798

未命名化合物

PRODUCTS

生成物

结构：C[Si](C)(C)CCOCn1ccnc1CN(Cc1nccn1COCC[Si](C)(C)C)C(=O)c1ccc(C=O)cc1

HCID86654293

未命名化合物

PROCEDURE

实验过程

The same procedure as a series of reactions of Example 17 was carried out, except that the compound 2 was used in place of the compound 16 and 4-formylbenzoic acid was used in place of 1H-imidazole-2-carboxylic acid, to obtain the title compound having the following physical properties.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-a4d3359abd7c4d25a96430fdac537b9a
来源数据集: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08822459B2
来源说明: uspto-grants-2014_09

反应 SMILES

[CH3:1][Si:2]([CH3:29])([CH3:28])[CH2:3][CH2:4][O:5][CH2:6][N:7]1[CH:11]=[CH:10][N:9]=[C:8]1[CH2:12][NH:13][CH2:14][C:15]1[N:16]([CH2:20][O:21][CH2:22][CH2:23][Si:24]([CH3:27])([CH3:26])[CH3:25])[CH:17]=[CH:18][N:19]=1.[CH:30]([C:32]1[CH:40]=[CH:39][C:35]([C:36](O)=[O:37])=[CH:34][CH:33]=1)=[O:31]>>[CH:30]([C:32]1[CH:40]=[CH:39][C:35]([C:36]([N:13]([CH2:14][C:15]2[N:16]([CH2:20][O:21][CH2:22][CH2:23][Si:24]([CH3:27])([CH3:26])[CH3:25])[CH:17]=[CH:18][N:19]=2)[CH2:12][C:8]2[N:7]([CH2:6][O:5][CH2:4][CH2:3][Si:2]([CH3:29])([CH3:28])[CH3:1])[CH:11]=[CH:10][N:9]=2)=[O:37])=[CH:34][CH:33]=1)=[O:31]