Benzyl Chloride → HCID 67119827, compound

Participants

Role	Name	HCID	Charge
Reactant	Benzyl Chloride	HCID 7503	—
Reactant	Potassium Carbonate	HCID 11430	—
Reactant	1,5-Dihydroxy-naphthlene-2-carboxylic acid	HCID 53872722	—
Solvent	Dimethylformamide	HCID 6228	—
Product	HCID 67119827	HCID 67119827	—

Reaction Steps

K2CO3 (2.45 g, 17.7 mmol), Dry DMF (5.4 mL), 1,5-Dihydroxy-naphthalene-2-carboxylic acid (0.539 g, 2.64 mmol), benzyl chloride (1.5 mL) Yield: 0.68 g of product (54%, 2 steps) Rf=0.38 (SiO2, 15% Hexanes/CH2Cl2). 1H NMR (400 MHz, CDCl3) δ 5.12 (s, 2H), δ 5.25 (s, 2H), δ 5.40 (s, 2H), δ 6.98 (d, J=7.3 Hz, 1H), δ 7.30-7.53 (m, 16H), δ 7.83 (d, J=8.7 Hz, 1H), δ 7.89 (d, J=8.7 Hz, 1H), δ 8.14 (d, J=8.7 Hz, 1H).

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08822515B2
Source dataset	uspto-grants-2014_09
ORD ID	ord-a8838e4c9271477f88911011941c5767
Source note	uspto-grants-2014_09