HCID 20075251, compound → HCID 20075284, compound

HRID 704050Notes

Reaction equation

HRID 704050 reaction equation
NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Cl:37][C:38]1[CH:43]=[CH:42][C:41]([S:44]([C:46]2[CH:51]=[CH:50][C:49]([C:52]3[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=3)=[CH:48][CH:47]=2)=[O:45])=[CH:40][C:39]=1[N+:58]([O-])=O>>[NH2:58][C:39]1[CH:40]=[C:41]([S:44]([C:46]2[CH:51]=[CH:50][C:49]([C:52]3[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=3)=[CH:48][CH:47]=2)=[O:45])[CH:42]=[CH:43][C:38]=1[Cl:37]

Participants

3

Reactant 2

HCID 20075251HCID 20075251, compoundHCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

Product 1

HCID 20075284HCID 20075284, compoundYield 85%

Procedure

Following the procedure described in Example 2 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of 4-(4-chloro-3-nitrophenylsulfinyl)-biphenyl, the title compound is obtained.

Sources & evidence

ORD record
ord-32eb08a84ac841e1a8f84e6480e9942f
Source dataset
uspto-grants-1991_01
Patent number
US04985463

Reaction notes

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