HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-Trimethylsilyl-N-methylacetamide → 1-Methyl-1-(N-methylacetamido)silacyclobutane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-Trimethylsilyl-N-methylacetamide | HCID 81953 | — |
| Reactant | Silacyclobutane, 1-chloro-1-methyl- | HCID 137554 | — |
| Product | 1-Methyl-1-(N-methylacetamido)silacyclobutane | HCID 15065924 | — |
Reaction Steps
To 30.02 g 1-chloro-1-methylsilacyclobutane was added 36.10 g N-methyl-N-(trimethylsilyl)acetamide. The reaction products were fractionally distilled. The title compound was isolated as a clear, colorless fluid with a boiling point of 68°-76° C. at 3.6 mm Hg. The yield was 31.56 g (86%). The product was identified by NMR and mass spectroscopy.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04985565 |
| Source dataset | uspto-grants-1991_01 |
| ORD ID | ord-b1a50ac77d5a4b2db5988d6d1a87bed9 |
| Source note | uspto-grants-1991_01 |