化工社化工社 化学情報印刷レポート · 研究参考用
1,1-Dichlorosilacyclobutane → 1,1-Diacetamidosilacyclobutane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,1-Dichlorosilacyclobutane | HCID 75373 | — |
| 反応物 | Acetamide, 2-(trimethylsilyl)- | HCID 357676 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 1,1-Diacetamidosilacyclobutane | HCID 20075523 | — |
反応手順
When 1.72 g of trimethylsilylacetamide was mixed with 0.92 g of 1,1-dichlorosilacyclobutane in 5 g of methylene chloride, a white precipitate formed. The precipitate dissoved upon shaking and slowly recrystallized as white needles. There was no trimethylchlorosilane detected in the residual fluid, indicating that the expected reaction to form 1,1-diacetamidosilacyclobutane did not occur.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04985565 |
| 出典データセット | uspto-grants-1991_01 |
| ORD ID | ord-c2cd10faa21e40fbbb19209d3ea4c1b8 |
| 出典メモ | uspto-grants-1991_01 |