HuagongsheHuagongshe Chemistry Print Report · For research reference only
CBr4 triphenylphosphine → (+) Methyl 6(R)-hydroxy-7-eicosynoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | CBr4 triphenylphosphine | HCID 11387777 | — |
| Reactant | 6-(+/-)-Hydroxy-7-eicosynoate | HCID 20073210 | — |
| Product | (+) Methyl 6(R)-hydroxy-7-eicosynoate | HCID 15003197 | — |
Reaction Steps
This compound was prepared by reaction of 6-(±)-hydroxy-7-eicosynoate (preparative example V) with CBr4 /Ph3P reagent in exactly the same manner as described in preparative example VIII. Note: By use of the corresponding 6-R, and 6-S alcohols (preparative example VI) the optically active (+) and (-) 6-bromo-7-eicosanoates were also obtained
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04988716 |
| Source dataset | uspto-grants-1991_01 |
| ORD ID | ord-e349fff5a5b642c591cd9535fbd5c52e |
| Source note | uspto-grants-1991_01 |