HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → HCID 13314942, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | HCID 86605019 | HCID 86605019 | — |
| Catalyst | Dimethylformamide | HCID 6228 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 13314942 | HCID 13314942 | 100% |
Reaction Steps
To a solution of (Z)-3-chloro-3-(4-chloro-phenyl)-prop-2-en-1-ol (101 mg) in toluene (3 ml) was added thionyl chloride (0.11 ml) and one drop of dimethylformamide. After 1 h, the solution was concentrated in vacuo to afford 120 mg of the desired allylic chloride (100%) as a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09174987B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-8d15d84513394232940d23c64b98ab2b |
| Source note | uspto-grants-2015_11 |