HRID70777

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID1004

Phosphoric acid

H3O4P

结构：COc1ccc2c3c1OC1C(=O)C=C[C@@]4(O)[C@@H](C2)N(C)CC[C@]314

HCID5359420

未命名化合物

结构：COc1ccc2c3c1O[C@H]1C(=O)C=C[C@H]4[C@@H](C2)N(C)CC[C@]314

HCID5459910

Codeinone

C18H19NO3

PRODUCTS

生成物

结构：COc1ccc2c3c1OC1C(=O)C=C[C@@]4(O)[C@@H](C2)N(C)CC[C@]314.COc1ccc2c3c1O[C@H]1C(=O)C=C[C@H]4[C@@H](C2)N(C)CC[C@]314

HCID131726012

未命名化合物

PROCEDURE

实验过程

25±1 mg of both codeinone and 14-hydroxycodeinone reference materials were weighed and transferred into a 100-mL volumetric flask, diluted to volume and dissolved with ˜0.85% phosphoric acid solution II.

WORKUP

后处理

customtransferred into a 100-mL volumetric flask
additiondiluted to volume

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-035af55de6134fabbd797eb93ee1d4e8
来源数据集: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08822687B2
来源说明: uspto-grants-2014_09

反应 SMILES

[CH3:1][N:2]1[C@@H:19]2[CH2:20][C:7]3[CH:8]=[CH:9][C:10]([O:21][CH3:22])=[C:11]4[O:12][C@H:13]5[C:14]([CH:16]=[CH:17][C@@H:18]2[C@:5]5([C:6]=34)[CH2:4][CH2:3]1)=[O:15].[CH3:23][N:24]1[C@@H:34]2[CH2:35][C:36]3[CH:41]=[CH:40][C:39]([O:42][CH3:43])=[C:38]4[O:44][CH:28]5[C:29]([CH:31]=[CH:32][C@:33]2([OH:45])[C@:27]5([C:37]=34)[CH2:26][CH2:25]1)=[O:30].P(=O)(O)(O)O>>[CH3:1][N:2]1[C@@H:19]2[CH2:20][C:7]3[CH:8]=[CH:9][C:10]([O:21][CH3:22])=[C:11]4[O:12][C@H:13]5[C:14]([CH:16]=[CH:17][C@@H:18]2[C@:5]5([C:6]=34)[CH2:4][CH2:3]1)=[O:15].[CH3:23][N:24]1[C@@H:34]2[CH2:35][C:36]3[CH:41]=[CH:40][C:39]([O:42][CH3:43])=[C:38]4[O:44][CH:28]5[C:29]([CH:31]=[CH:32][C@:33]2([OH:45])[C@:27]5([C:37]=34)[CH2:26][CH2:25]1)=[O:30]