HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 708920Generated: October 30, 2026
Potassium Acetate → HCID 131733880, compound
https://huagongshe.com/reaction/708920
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Potassium Acetate | HCID 517044 | — |
| Reactant | Bis(neopentyl glycolato)diboron | HCID 2734316 | — |
| Reactant | HCID 118093126 | HCID 118093126 | — |
| Catalyst | Bis(cyclopenta-1,4-dien-1-yl(diphenyl)phosphane);dichloropalladium;iron(2+) | HCID 178418228 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | HCID 131733880 | HCID 131733880 | 68.2% |
Reaction Steps
To a reaction tube was added 37C (480 mg, 0.76 mmol), 5,5,5′,5′-tetramethyl-2,2′-bi(1,3,2-dioxaborinane) (206 mg, 0.912 mmol), KOAc (186 mg, 1.900 mmol), Pd(dppf)Cl2 (125 mg, 0.152 mmol) in DMSO (1.5 ml). The tube was filled with Ar, sealed and stirred at 85° C. for 2 h. The mixture was quenched with water, and extracted with EtOAc. The combined organic layer was filtered though silica gel and concentrated. The crude product was purified by flash chromatography to give 37D (309 mg, 0.518 mmol, 68.2% yield). MS (ESI) m/z: 597.4 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US09174974B2 |
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| Source dataset | uspto-grants-2015_11 |
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| ORD ID | ord-121eca944c684d248cbdd32780ee1dce |
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| Source note | uspto-grants-2015_11 |
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