2-(Chloromethyl)-5-methylpyridine → HCID 86731538, compound

HRID 709043Notes

Reaction equation

HRID 709043 reaction equation
[CH2:1]([C:3]1[CH:24]=C[C:6]([CH2:7][S:8][C:9]2[CH:10]=[C:11]([O:19][CH2:20][O:21][CH3:22])[C:12](=[O:18])[N:13]([CH2:15][O:16][CH3:17])[CH:14]=2)=[CH:5][CH:4]=1)C.ClCC1C=CC(C)=C[N:28]=1>>[CH3:22][O:21][CH2:20][O:19][C:11]1[C:12](=[O:18])[N:13]([CH2:15][O:16][CH3:17])[CH:14]=[C:9]([S:8][CH2:7][C:6]2[CH:5]=[CH:4][C:3]([CH3:1])=[CH:24][N:28]=2)[CH:10]=1

Participants

3

Reactant 2

HCID 5880562-(Chloromethyl)-5-methylpyridineHCID 867315275-[(4-ethylbenzyl)sulfanyl]-3-(methoxymethoxy)-1-(methoxymethyl)pyridin-2(1H)-one2×

Product 1

HCID 86731538HCID 86731538, compound

Procedure

Prepared as described for 5-[(4-ethylbenzyl)sulfanyl]-3-(methoxymethoxy)-1-(methoxymethyl)pyridin-2(1H)-one (Intermediate 17) but using 2-chloromethyl-5-methylpyridine instead of 1-(chloromethyl)-4-ethylbenzene.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-599c67d68d2742b7bec51a13ebbf5e17
Source dataset
uspto-grants-2015_11
Patent number
US09180122B2

Reaction notes

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