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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 709340Generated: October 30, 2026

Benzylamine → Dibenzylamine

https://huagongshe.com/reaction/709340

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzylamineHCID 7504—
CatalystPalladiumHCID 23938—
SolventAcetonitrileHCID 6342—
ProductDibenzylamineHCID 765691%

Reaction Conditions

Temperature90 °C

Reaction Steps

To carry out the oxidative condensation, benzylamine (0.5 mmol) was heated with catalyst Pd@ba-GO (10 mg) and solvent CH3CN (0.2 mL) at 90° C. in a flask open to air for 6 hours, and then stirred also at 90° C. under H2 gas (1 atm) for 6 hours to obtain dibenzylamine. An unexpectedly high yield of 91% was achieved.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS09180442B2
Source datasetuspto-grants-2015_11
ORD IDord-93f19989abb9418cacc99c520cf99ffe
Source noteuspto-grants-2015_11