Formic Acid → HCID 66726619, compound

Participants

Reaction Conditions

Reaction Steps

To a solution of the product of Step E (0.4 g, 0.78 mmol) in HCOOH (3 ml) (CH2O)n (0.026 g, 0.87 mmol) was added and the mixture was stirred for 18 h at 60° C. This was evaporated to dryness and the residue was purified by FCC (SiO2) to give the desired product (0.17 g, 41%), as light yellow paste. 1H-NMR (CDCl3) 1.36 (d, 6H, J=6 Hz); 1.74 (s, 6H); 2.03 (s, 3H); 2.08 (s, 6H); 2.7 (tr, 2H, J=5.91 Hz); 3.10 (tr, 2H, J=5.99 Hz); 3.91 (5, 2H); 4.55-4.64 (m, 1H); 6.53 (s, 1H); 6.82 (s, 1H).

Provenance & Evidence