2-Bromopropane → 2-(1-Admantyl)-4-iodo-1-(octyloxy)benzene

Participants

Reaction Steps

When 1-bromooctane was substituted for 2-bromopropane and 2-(1-admantyl)-4-iodo-phenol was substituted for 3-(1-admantyl)-4-hydroxybenzaldehyde in Example 60, Step A, the identical process afforded the title compound in 72% yield. 1H-NMR (CDCl3) 0.87 (tr, 3H, J=5.22 Hz); 1.26-1.29 (m, 9H); 1.51-1.53 (m, 2H); 1.75 (s, 6H); 1.81-1.86 (m, 2H); 2.07 (5, 9H); 3.91 (tr, 2H, J=6.28 Hz); 6.58-6.6 (d, 1H, J=8.21 Hz); 7.39-7.42r(m, 2H).

Provenance & Evidence