Dinitrobenzonitrile → HCID 12715773, compound

HRID 711763Notes

Reaction equation

HRID 711763 reaction equation
[N+](C1C=CC=C([N+]([O-])=O)C=1C#N)([O-])=O.[CH2:15]([NH:18][C:19]1[CH:26]=[CH:25][CH:24]=[C:23]([N+:27]([O-:29])=[O:28])[C:20]=1[C:21]#[N:22])[CH2:16][CH3:17].C(N)CC>>[CH2:15]([NH:18][C:19]1[CH:26]=[CH:25][CH:24]=[C:23]([N+:27]([O-:29])=[O:28])[C:20]=1[C:21]#[N:22])[CH2:16][CH3:17]

Participants

3

Reactant 2

HCID 520718DinitrobenzonitrileHCID 67398810HCID 67398810, compound

Product 1

HCID 12715773HCID 12715773, compound

Procedure

Prepared as in Example 90c from 2,6-dinitrobenzonitrile and propylamine 2-propylamino-6-nitrobenzonitrile (0.53 g, 86%). 1H NMR (400 MHz, DMSO-d6) δ 0.88 (t, J=7.2 Hz, 3H), 1.51-1.57 (m, 2H), 3.22 (q, J=5.6, J=6.4, 2H), 6.60-6.63 (m, NH), 7.22 (d, J=8.8 Hz, 1H), 7.40 (d, J=7.6 Hz, 1H), 7.58 (t, J=8.4 Hz, 1H).

Sources & evidence

ORD record
ord-98d19e4bf4a1402eb1d1f682984b667d
Source dataset
uspto-grants-2015_11
Patent number
US09181276B2

Reaction notes

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