HuagongsheHuagongshe Chemistry Print Report · For research reference only
(+)-2-Butanol → (S)-2-sec-Butoxy-6-nitrobenzonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (+)-2-Butanol | HCID 444683 | — |
| Reactant | Dinitrobenzonitrile | HCID 520718 | — |
| Product | (S)-2-sec-Butoxy-6-nitrobenzonitrile | HCID 67401509 | 85.2% |
Reaction Steps
Prepared as in Example 111c from (S)-butan-2-ol and 2,6-dinitrobenzonitrile in 85.2% yield. 1H NMR (400 MHz, DMSO-d6) δ 0.94 (t, J=7.6 Hz, 3H), 1.29 (d, J=6.4 Hz, 1H), 1.69 (m, 2H), 4.72 (m, 1H), 7.74 (dd, J=6.8, 2.4 Hz, 1H), 7.86 (m, 1H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09181276B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-50e81c308b3e469399b1b46962166506 |
| Source note | uspto-grants-2015_11 |