HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methoxybenzyl alcohol → 2-Nitro-6-(2-methoxybenzyloxy)benzonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methoxybenzyl alcohol | HCID 69154 | — |
| Reactant | Dinitrobenzonitrile | HCID 520718 | — |
| Product | 2-Nitro-6-(2-methoxybenzyloxy)benzonitrile | HCID 66746302 | 58% |
Reaction Steps
Prepared as in Example 111c from 2,6-dinitrobenzonitrile and 2-methoxybenzyl alcohol in 58% yield. 1H NMR (400 MHz, DMSO) δ 3.82 (s, 3H), 5.34 (s, 2H), 6.99 (t, J=7.6 Hz, 1H), 7.08 (d, J=8.4 Hz, 1H), 7.37 (t, J=8.4 Hz, 1H), 7.46 (d, J=6.0 Hz, 1H), 7.81 (d, J=7.6 Hz, 1H), 7.93-7.87 (m, 2H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09181276B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-5c29e4e4302d4ac88dac275963a638b8 |
| Source note | uspto-grants-2015_11 |