Isopentyldiol → HCID 67400326, compound

HRID 711851Notes

Reaction equation

[CH3:1][C:2]([OH:7])([CH3:6])[CH2:3][CH2:4][OH:5].[N+:8]([C:11]1[CH:18]=[CH:17][CH:16]=[C:15]([N+]([O-])=O)[C:12]=1[C:13]#[N:14])([O-:10])=[O:9]>>[OH:7][C:2]([CH3:6])([CH3:1])[CH2:3][CH2:4][O:5][C:15]1[CH:16]=[CH:17][CH:18]=[C:11]([N+:8]([O-:10])=[O:9])[C:12]=1[C:13]#[N:14]

Participants

Reactant 2

HCID 247470Isopentyldiol

HCID 520718Dinitrobenzonitrile

Product 1

HCID 67400326HCID 67400326, compoundYield 81%

Procedure

Prepared as in Example 215c from 3-methylbutane-1,3-diol and 2,6-dinitrobenzonitrile in 81% yield. MS 251 (MH+).

Sources & evidence

ORD record: ord-2f368fd17f194917bfef0329a3c7b3e2
Source dataset: uspto-grants-2015_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09181276B2

Reaction notes

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