HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → HCID 86676834, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Dimethyl Carbonate | HCID 12021 | — |
| Reactant | Methylcarbonate | HCID 4585885 | — |
| Reactant | N,N,N-Trihexylhexan-1-aminium hydroxide | HCID 13998878 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | HCID 86676834 | HCID 86676834 | — |
Reaction Steps
10 g of a 10% b.w. solution of tetrahexylammonium hydroxide (2.7 mmole) in methanol was mixed with 1 g (11 mmoles) of dimethylcarbonate (DMC) to yield a clear, colorless solution. Titration in 2-propanol with aqueous HCl after 24 hours revealed an equivalence point at a lower pH for the blocked versus the unblocked form and indicated complete blocking to 0.26 meq methylcarbonate per g solution.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09181452B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-99384695ad134670ae6c07482d09b26e |
| Source note | uspto-grants-2015_11 |