Potassium Carbonate → HCID 86700954, compound

Participants

Reaction Steps

A mixture solution of (6-Iododibenzo[b,d]furan-4-yl)triphenylsilane (6.60 g, 11.95 mmol), (3-chlorophenyl)boronic acid (2.80 g, 17.92 mmol), Pd(PPh3)4 (0.138 g, 0.119 mmol) and K2CO3 (3.30 g, 23.89 mmol) in toluene (100 mL) and water (15 mL) was refluxed under nitrogen for 24 hours. After cooling to room temperature, the organic phase was isolated and the solvent was evaporated. The residue was purified by column chromatography on silica gel with hexane/DCM (4/1, v/v) as eluent to yield (6-(3-chlorophenyl)dibenzo[b,d]furan-4-yl)triphenylsilane (3.7 g, 58%) as a white solid.

Provenance & Evidence