Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Nitroethane | HCID 6587 | — |
| Reactant | 4-Nitrobenzoyl chloride | HCID 8502 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | Benzophenone | HCID 3102 | — |
Reaction Steps
A solution of polymer in a suitable solvent (nitroethane, dichloromethane, chloroform) was treated with 4-nitro benzoyl chloride (1 eq) and aluminium chloride (1.2 eq). The solution was stirred at room temperature or at 40° C. then quenched with water. The organic layer was collected and washed with 1M HCl and 1M NaOH solutions sequentially. Concentration of the organic layer yielded the product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09193678B2 |
|---|
| Source dataset | uspto-grants-2015_11 |
|---|
| ORD ID | ord-39a02655e7c146e5bb7c6b2b4bd1fc53 |
|---|
| Source note | uspto-grants-2015_11 |
|---|
