反应详情

温度

60 °C

A mixture of octadecanoic acid (170 mg, 0.6 mmol) and thionyl chloride (4 mL) was heated at 60° C. for 1 hour. The mixture was then cooled to room temperature, whereupon it was concentrated in vacuo. Residue from this mixture was then dissolved in CH2Cl2 (10 mL), whereupon pyridine (5 equivalents) and 4-(aminobutyl)-1,10-phenanthroline (1 equivalent) (Wang et al., Adv. Funct. Mater., 12, 415-419 (2002)) were added. The resulting mixture was stirred at room temperature overnight and then poured into H2O. The resulting precipitate was collected by suction filtration and dried to a constant weight to give 4-(4-(octadecanoylamino)butyl)-1,10-phenanthroline.

1. temperatureThe mixture was then cooled to room temperature, whereupon it
2. concentrationwas concentrated in vacuo
3. dissolutionResidue from this mixture was then dissolved in CH2Cl2 (10 mL)
4. filtrationThe resulting precipitate was collected by suction filtration
5. customdried to a constant weight