HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Dithionite → 2-Hydroxyiminostilbene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Dithionite | HCID 24489 | — |
| Reactant | 2h-dibenzo[b,f]azepin-2-one | HCID 276457 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 2-Hydroxyiminostilbene | HCID 13103864 | 65% |
Reaction Steps
Title compound 374 (170 mg, 0.82 mmol) was solubilized in CHCl3 (5 mL) and a saturated solution of Na2S2O4 in water was added (20 mL). The mixture was stirred for 3 hours. The 2 layers were split and the organic layer was dried over sodium sulfate, filtered and evaporated to afford title compound 375 (110 mg, 65%). MS (m/z): 209.9 (M+H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193749B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-4f0b5f48cf83455180d7dd053a210197 |
| Source note | uspto-grants-2015_11 |