HRID718507

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID3102

Benzophenone

C13H10O

HCID7187

Benzoyl peroxide

C14H10O4

HCID7410

Acetophenone

C8H8O

HCID122825

2,4-Diethyl-9H-thioxanthen-9-one

C17H16OS

HCID618848

9H-Thioxanthen-9-one, 2-chloro-

C13H7ClOS

结构：[N-]=[N+]=Nc1ccc(C=Cc2ccc(N=[N+]=[N-])cc2S(=O)(=O)O)c(S(=O)(=O)O)c1

HCID178514490

未命名化合物

PRODUCTS

生成物

HCID84835

Benzeneacetic acid, .alpha.-oxo-, methyl ester

C9H8O3

HCID90794

2-(2-Methylpropoxy)-1,2-diphenylethanone

C18H20O2

PROCEDURE

实验过程

Examples of the photopolymerization initiator include acetophenone, benzophenone, benzyl dimethyl ketanol, benzoyl peroxide, 2-chlorothioxanthone, 1,3-bis(4′-azidobenzal)-2-propane, 1,3-bis(4′-azidobenzal)-2-propane-2′-sulfonic acid, and 4,4′-diazidostilbene-2,2′-disulfonic acid. Examples of commercially available photopolymerization initiators include “IRGACURE (trade mark)-184”, “IRGACURE (trade mark)-369”, “DAROCUR (trade mark)-1173”, and “Lucirin-TPO” produced by BASF Corporation, “KAYACURE (trade mark) DETX” and “KAYACURE (trade mark) OA” produced by NIPPON KAYAKU Co., Ltd., “VICURE 10” and “VICURE 55” produced by Stauffer Chemical Co., “TRIGONAL PI” produced by Akzo Chemicals B.V., “Sandorey 1000” produced by Sandoz, “DEAP” produced by Upjohn Co., Ltd., and “Biimidazole” produced by Kurogane Kasei Co., Ltd.

WORKUP

后处理

custom”, “DAROCUR (trade mark)-1173”, and “Lucirin-TPO” produced by BASF Corporation, “
customproduced by NIPPON KAYAKU Co

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-3b2cb43a69cc47f8bca35bd3677be493
来源数据集: uspto-grants-2015_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09193906B2
来源说明: uspto-grants-2015_11

反应 SMILES

[C:1]([C:4]1[CH:9]=CC=C[CH:5]=1)(=[O:3])C.[C:10]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)(=[O:17])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[C:24](OO[C:34](=[O:41])[C:35]1[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=1)(=O)C1C=CC=CC=1.ClC1C=CC2SC3C(=CC=CC=3)[C:46](=[O:57])C=2C=1.N(C1C=C(S(O)(=O)=O)C(C=CC2C(S(O)(=O)=O)=CC(N=[N+]=[N-])=CC=2)=CC=1)=[N+]=[N-].CCC1C=C2[C:94](C3C(SC2=C(CC)C=1)=CC=CC=3)=[O:95]>>[CH3:5][CH:4]([CH2:1][O:3][CH:18]([C:10]([C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)=[O:17])[C:23]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:24]=1)[CH3:9].[CH3:94][O:95][C:46]([C:34]([C:35]1[CH:36]=[CH:37][CH:38]=[CH:39][CH:40]=1)=[O:41])=[O:57]