HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,7-Dimethyloctanal → (5,9-Dimethyldec-2-enyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,7-Dimethyloctanal | HCID 110747 | — |
| Reactant | Phenethyltriphenylphosphonium bromide | HCID 10863251 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | (5,9-Dimethyldec-2-enyl)benzene | HCID 86702758 | 55.1% |
Reaction Steps
Starting from phenethyltriphenylphosphonium bromide (3.85 g, 8.61 mmol, 1.0 equiv.), n-BuLi (1.6 M in hexanes, 5.4 mL, 8.61 mmol, 1.0 equiv.) and 3,7-dimethyloctanal (2.02 g, 12.9 mmol, 1.5 equiv.), 1.16 g (55%) of the title compound as a colorless oil was obtained after purification by flash chromatography on SiO2 (cyclohexane).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-6f766b26a7a44141996d4eb59e0ee4e8 |
| Source note | uspto-grants-2015_11 |