HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4-Dimethyl-3-cyclohexene carboxaldehyde → (3-(2,4-Dimethylcyclohex-3-enyl)allyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4-Dimethyl-3-cyclohexene carboxaldehyde | HCID 93375 | — |
| Reactant | Phenethyltriphenylphosphonium bromide | HCID 10863251 | — |
| Product | (3-(2,4-Dimethylcyclohex-3-enyl)allyl)benzene | HCID 86702760 | 61.4% |
Reaction Steps
Starting from phenethyltriphenylphosphonium bromide (3.67 g, 8.20 mmol, 1.0 equiv.), n-Buli (1.6 M in hexanes, 5.1 mL, 8.20 mmol, 1.0 equiv.) and 2,4-dimethylcyclohex-3-enecarbaldehyde (1.70 g, 12.3 mmol, 1.5 equiv.), 1.14 g (61%) of the title compound as a colorless oil was obtained after purification by flash chromatography on SiO2 (cyclohexane).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-fd3b54b74f0940d2840aa364e43a0061 |
| Source note | uspto-grants-2015_11 |