HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Acetylnaphthalene → HCID 86702767, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Acetylnaphthalene | HCID 7122 | — |
| Reactant | Phenethyltriphenylphosphonium bromide | HCID 10863251 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | HCID 86702767 | HCID 86702767 | 54% |
Reaction Steps
Starting from phenethyltriphenylphosphonium bromide (2.30 g, 5.14 mmol, 1.0 equiv.), n-BuLi (1.6 M in hexanes, 3.2 mL, 5.14 mmol, 1.0 equiv.) and 1-(naphthalen-2-yl)ethanone (1.22 g, 7.20 mmol, 1.4 equiv.), 0.71 g (54%) of the title compound as a yellow oil was obtained after purification by flash chromatography on SiO2 (cyclohexane/EtOAc 995:5).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-5d99183ba7564bc79b21aaa3b7172510 |
| Source note | uspto-grants-2015_11 |