HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenethyltriphenylphosphonium bromide → HCID 86702772, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenethyltriphenylphosphonium bromide | HCID 10863251 | — |
| Reactant | HCID 57429401 | HCID 57429401 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | HCID 86702772 | HCID 86702772 | 61.1% |
Reaction Steps
Starting from phenethyltriphenylphosphonium bromide (2.60 g, 5.81 mmol, 1.0 equiv.), n-BuLi (1.3 M in hexanes, 4.5 mL, 5.81 mmol, 1.0 equiv.) and 3-(3-tert-butylcyclohexyl)propanal (1.45 g, 7.39 mmol, 1.3 equiv.), 1.01 g (61%) of the title compound as a colorless oil was obtained after purification by flash chromatography on SiO2 (cyclohexane).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-f660562352cb43eeadb1fe4efb3dec68 |
| Source note | uspto-grants-2015_11 |