HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenethyltriphenylphosphonium bromide → HCID 86702773, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenethyltriphenylphosphonium bromide | HCID 10863251 | — |
| Reactant | [4-(2-Methylbutan-2-yl)cyclohexyl]acetaldehyde | HCID 11333063 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | HCID 86702773 | HCID 86702773 | 48.8% |
Reaction Steps
Starting from phenethyltriphenylphosphonium bromide (2.00 g, 4.47 mmol, 1.0 equiv.), n-BuLi (1.6 M in hexanes, 2.8 mL, 4.47 mmol, 1.0 equiv.) and 2-(4-tert-pentylcyclohexyl)acetaldehyde (1.32 g, 6.71 mmol, 1.5 equiv.), 0.62 g (48%) of the title compound as a colorless oil was obtained after purification by flash chromatography on SiO2 (cyclohexane).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-9240ae214feb4f6d9a2582ed6f3e5ddc |
| Source note | uspto-grants-2015_11 |