HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4-Methoxybenzyl)(triphenyl)phosphonium bromide → HCID 67982889, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4-Methoxybenzyl)(triphenyl)phosphonium bromide | HCID 2734885 | — |
| Reactant | trans-4-Decen-1-al | HCID 5702654 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 67982889 | HCID 67982889 | 72% |
Reaction Steps
Starting from (4-methoxyphenyl)methyltriphenylphosphonium bromide (14.0 g, 30.2 mmol, 1.0 equiv.), KtBuO (34 mL, 34.0 mmol, 1.1 equiv., 1M in THF) and (E)-dec-4-enal (5.59 g, 36.3 mmol, 1.2 equiv.), 5.59 g (72%) of the title compound was obtained after purification by flash chromatography on SiO2 (cyclohexane/EtOAc 99:1) as a light yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09193935B2 |
| Source dataset | uspto-grants-2015_11 |
| ORD ID | ord-219e9a937ab34cd8b3e768a2b7dc4147 |
| Source note | uspto-grants-2015_11 |